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Atalanta continued their dream debut Champions League campaign on Wednesday with a 4-1 win over Valencia in an entertaining last-16 first-leg clash.
Atletico Madrid's disappointing season continued as they shared the spoils with Valencia in a thrilling 2-2 draw in La Liga at Mestalla on Friday.
Getafe underlined their ambition to qualify for the Champions League by outplaying direct rivals Valencia and beating them 3-0 at home on Saturday.
Roberto Soldado scored a stoppage time penalty to send Granada into the Copa del Rey semi-finals with a 2-1 win over holders Valencia on Tuesday.
The negotiations between Barcelona and Valencia for striker Rodrigo are on the verge of collapse, sources close to the Catalan club have said.
Star players earned wins in Quique Setien's first two games as Barcelona manager, but there was no rescue job during a limp defeat at Mestalla.
Quique Setien's honeymoon period as Barcelona coach is over after a Jordi Alba own goal and a strike from Maxi Gomez helped Valencia to a 2-0 win.
Real Madrid made short work of Valencia in the semifinal of the Spanish Super Cup, beating their fellow La Liga side 3-1 in Jeddah, Saudi Arabia.
Real Madrid will play Manchester City in the Champions League round of 16, and holders Liverpool will face Atletico Madrid.
Karim Benzema smashed the ball into the roof of the net in second-half stoppage time to give Real Madrid a 1-1 draw at Valencia in La Liga.
Ajax Amsterdam have been eliminated from the Champions League following their loss to Valencia on Tuesday.
Chelsea will have to wait to book their place in the Champions League round of 16 after a late goal earned Valencia a 2-2 draw.
Valencia breathed life into their hopes of qualifying for the Champions League round of 16 to come from behind to beat Lille 4-1.
Sevilla missed out on the chance to go level on points with La Liga leaders Barcelona as they were held to a 1-1 draw away to Valencia on Wednesday
Substitute Jonathan Ikone blasted home an equaliser deep into stoppage time to give Lille a 1-1 draw against 10-man Valencia.